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In AutoCAD, the default option will let you add material to the entire object but to add materials to selected faces you need to use some workarounds explained in this article. Adding material to 3D solid. In this example, I will use this Oldham's coupling 3D drawing and add materials to it.

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Solution: To apply an existing material to the faces of a 3D solid object: On the command line, enter SOLIDEDIT. When prompted, select Face > Material. When prompted, select the face (s) of the solid object. Enter the name of the existing material that you want to apply. Press ENTER twice to exit the command. Product versions 2007 and later:

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